Square-planar Pd(II), Pt(II), and Au(III) terpyridine complexes: Their syntheses, physical properties, supramolecular constructs, and biomedical activities

被引：578

作者：

Eryazici, Ibrahim ^{[1
]}

Moorefield, Charles N. ^{[3
]}

Newkome, George R. ^{[1
,2
,3
]}

机构：

[1] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA

[2] Univ Akron, Dept Chem, Akron, OH 44325 USA

[3] Univ Akron, Maurice Morton Inst Polymer Sci, Akron, OH 44325 USA

来源：

CHEMICAL REVIEWS | 2008年 / 108卷 / 06期

关键词：

D O I：

10.1021/cr0781059

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A review on square-planar terpyridine complexes has been done regarding its syntheses, physical and structural properties, supramolecular chemistry, and biomedical applications. Other topics being discussed include: the single X-ray crystal structures and their molecular packing; dimerization and its constant; fluxionality; the applications of mononuclear terpyridine complexes; molecular stacking and induced self-assembly; the metallo-supramolecular terpyridine architectures; dyads and triads; supramolecular self-assemblies; molecular recognition by host-guest interaction; multimetallic peptide scaffolds; biological activities; DNA intercalation; covalent binding to biomolecules; labeling biomolecules; and finally, cytotoxicity.

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收藏

页码：1834 / 1895

页数：62

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