A platinum(II) complex containing carbon-bonded 'nitromethane':: [Pt(CH2NO2)(2,2′:6′,2"-terpyridine)]+

被引：18

作者：

Akiba, M ^{[1
]}

Sasaki, Y ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Kita Ku, Sapporo, Hokkaido 060, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 02期

关键词：

crystal structures; platinum complexes; nitromethyl complexes; photochemistry;

D O I：

10.1016/S1387-7003(98)00016-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

X-ray structural analysis disclosed a carbon-bonded nitromethyl platinum(II) complex, [Pt(CH2NO2)(terpy)](+)(terpy=2,2':6',2'-terpyridine). The perchlorate salt was readily obtained by adding HClO4 to the nitromethane solution of [Pt(OH)(terpy)](+). The emission spectra of the two salts, perchlorate and tetraphenylborate, are significantly different, suggesting a different extent of the intermolecular interaction between them. (C) 1998 Elsevier Science S.A.

引用

页码：61 / 63

页数：3

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