Stereoselective construction of quaternary stereocenters

被引:479
作者
Christoffers, J [1 ]
Baro, A [1 ]
机构
[1] Univ Stuttgart, Inst Organ Chem, D-70569 Stuttgart, Germany
关键词
asymmetric catalysis; asymmetric synthesis; C-C coupling; chiral auxiliaries; quaternary stereocenters; synthetic methods;
D O I
10.1002/adsc.200505165
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Quaternary stereocenters are a particular challenge for stereoselective synthesis. With a central view on this specific structural issue, selected examples from the recent literature are highlighted in order to evaluate the state of the art of asymmetric C-C bond formation. The review is divided into sections on addition and substitution reactions, rearrangements and cycloaddition reactions.
引用
收藏
页码:1473 / 1482
页数:10
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