Cu(II) Schiff-base complex with [N3O] binding site and a pendant S-methylisothiosemicarbazide arm

被引：3

作者：

Gradinaru, J

Forni, A

Buza, N

Gerbeleu, N

机构：

[1] CNR, Ist Sci & Tecnol Mol, I-20133 Milan, Italy

[2] Moldavian Acad Sci, Inst Chem, MD-2028 Kishinev, Moldova

来源：

INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 03期

关键词：

Cu(II) complexes; square-planar complexes; tetradentate [N3O] isothiosemicarbazide-based ligands;

D O I：

10.1016/j.ica.2003.09.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A neutral four-coordinate (CuN3O)-N-II complex with Shiff base ligand, product of template assembling of two S-methylisothiosemicarbazide units with benzoylacetone and nitromalondialdehyde, was synthesized by two steps procedure via (CuN2O2)-N-II chelate precursor and was fully characterized by elemental analysis, IR, UV-Vis, ESR spectra and magnetochemistry. X-ray analysis confirms its structural assignment. The assembling ligand assumes an acyclic structure of '4+1' type where a non-bonding interaction between the metal and the amino group of one S-methylisothiosemicarbazide unit takes place. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：875 / 880

页数：6

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