Synthesis of 5,10,15,20-tetrakis(4-tert-butyl-2,6-dicarboxyphenyl)porphyrin:: A versatile bis-faced porphyrin synthon for D4-symmetric chiral porphyrins

被引：18

作者：

Nakagawa, H

Nagano, T

Higuchi, T ^{[1
]}

机构：

[1] Nagoya City Univ, Fac Pharmaceut Sci, Mizuho Ku, Nagoya, Aichi 4678603, Japan

[2] Univ Tokyo, Grad Sch Pharmaceut Sci, Bunkyo Ku, Tokyo 1130033, Japan

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 12期

关键词：

D O I：

10.1021/ol015780a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A versatile his-faced porphyrin synthon, 5,10,15,20-tetrakis(4-tert-butyl-2,6-dicarboxyphenyl)porphyrin, was synthesized. The eight carboxyl groups were readily converted into various amide groups, and condensation with chiral amines led to various D-4-symmetric chiral porphyrins with rigid structures.

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页码：1805 / 1807

页数：3

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