Organometallic thermochemistry at CQE-IST. An overview

被引：13

作者：

Diogo, HP

da Piedade, MEM

Simoes, JAM ^{[1
]}

Teixeira, C

机构：

[1] Inst Super Tecn, Ctr Quim Estrutural, P-1049001 Lisbon, Portugal

[2] Univ Lisbon, Dept Quim & Bioquim, Fac Ciencias, P-1749016 Lisbon, Portugal

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 632卷 / 1-2期

关键词：

thermochemistry; bond enthalpies; entropy changes;

D O I：

10.1016/S0022-328X(01)00861-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A brief overview of the organometallic thermochemistry research made at Lisbon, for over 25 years is given in this paper. The examples presented illustrate how those studies motivated the building of new instrumentation, and how the obtained results were used to discuss the 'strength' of the transition metal-ligand bonds, rationalise reactivity trends, and develop empirical methods to estimate thermochemical data. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：188 / 196

页数：9

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