Synthesis and photophysical studies of a new nonaggregated C60-silicon phthalocyanine-C60 triad

被引：72

作者：

Martin-Gomis, Luis

Ohkubo, Kei

Fernandez-Lazaro, Fernando

Fukuzumi, Shunichi

Sastre-Santos, Angela ^{[1
]}

机构：

[1] Univ Miguel Hernandez, Inst Bioingn, Div Quim Organ, Alicante 03202, Spain

[2] Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, SORST,Japan Sci & Technol Agcy, Suita, Osaka 5650871, Japan

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 17期

关键词：

D O I：

10.1021/ol701444d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A C-60-SiPc-C-60 triad showing no aggregation is synthesized and characterized. Photoexcitation of the triad results in formation of the charge-separated state by photoinduced electron transfer from the singlet excited state of the SiPc moiety to the C-60 moiety. The charge-separated state has a lifetime of 5 ns in benzonitrile at 298 K.

引用

页码：3441 / 3444

页数：4

共 41 条

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[Anonymous], PHTHALOCYANINES SYNT

[2]

[Anonymous], 2002, FULLERENES SYNTHESIS

[3] Synthesis and photophysical characterization of a titanium(IV) phthalocyanine-C60 supramolecular dyad [J].