Fluorinated carbonyl and olefinic compounds: Basic character and asymmetric catalytic reactions

被引：433

作者：

Mikami, K ^{[1
]}

Itoh, Y ^{[1
]}

Yamanaka, M ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 01期

关键词：

D O I：

10.1021/cr030685w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The basic character and asymmetric catalytic reactions of fluorinated carbonyl and olefinic compounds were studied. The classification of synthetic methods for fluorine-containing compounds which include carbon-fluorine bond-forming reactions and carbon-carbon bond-forming reactions was also described. The enolate alkylation of carbonyl compounds was one of the most basic methodologies for carbon-carbon bond-forming reactions. The asymmetric F-C reaction of a vinyl ether with fluoral, catalyzed by (R)-BINOLate-Ti complex, derived from BINOL and TiCl2(OiPr)2 was discussed.

引用

页码：1 / 16

页数：16

共 200 条

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