Characterization of plasma treated Pd/HZSM-5 catalyst for methane combustion

In this work, a novel glow discharge plasma treatment of Pd/HZSM-5 catalyst, followed by calcination thermally, has been conducted. Such prepared catalyst presents a higher catalytic activity and an enhanced stability over the catalyst prepared without plasma treatment. The methane conversion over the plasma treated catalyst is close to 100% at 450 degreesC, but it is only ca. 50% at the same temperature over the catalyst without plasma treatment. The XPS, H-2 chemisorption and XRD characterizations confirm an enhanced dispersion has been achieved with the plasma reduction (during treatment) followed by oxidation (during calcination). Upon FT-IR analyses, the plasma treatment, followed by calcination thermally, also leads to enhanced Bronsted and Lewis acidities. The amount of Bronsted acid sites of the plasma treated Pd/HZSM-5 catalyst is 1.13 times larger than that of the catalyst without plasma treatment, while the amount of Lewis acid sites of the plasma treated Pd/HZSM-5 catalyst is 1.21 times higher. The enhanced acidities are definitely helpful to increase the dispersion of PdO over the support and improve the interaction between PdO and HZSM-5 support, which leads to a remarkable improvement in the catalyst stability. (C) 2003 Elsevier B.V. All rights reserved.