Ambipolarity in Benzobisthiadiazole-Based Donor-Acceptor Conjugated Polymers

被引:121
作者
Yuen, Jonathan D. [1 ]
Kumar, Rajeev [2 ]
Zakhidov, Dante [1 ]
Seifter, Jason [1 ]
Lim, Bogyu [1 ]
Heeger, Alan J. [1 ]
Wudl, Fred [1 ]
机构
[1] Univ Calif Santa Barbara, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA
[2] Nanoterra Inc, Brighton, MA 02135 USA
基金
美国国家科学基金会;
关键词
FIELD-EFFECT TRANSISTORS; LOW-BANDGAP; N-CHANNEL; DIKETOPYRROLOPYRROLE; SEMICONDUCTORS; POLYTHIOPHENES; COPOLYMERS; TRANSPORT; ELECTRON;
D O I
10.1002/adma.201101134
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A family of four new DA polymers, in which the acceptor moiety benzobisthiadiazole was paired with four different donor moieties, has been synthesized. Surprisingly, all members of the family exhibit balanced ambipolar behavior, despite polymer to polymer mobilities varying from 10(-4) cm(2) V-1 s(-1) to 10(-1) cm(2) V-1 s(-1). Applications in single component CMOS integrated circuits are envisioned.
引用
收藏
页码:3780 / +
页数:7
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