Allosteric pitch length tuning of a dinuclear double helicate

被引:15
作者
Baylies, CJ [1 ]
Jeffery, JC [1 ]
Miller, TA [1 ]
Moon, R [1 ]
Rice, CR [1 ]
Riis-Johannessen, TR [1 ]
机构
[1] Univ Huddersfield, Dept Chem & Biol Sci, Huddersfield HD1 3DH, W Yorkshire, England
关键词
D O I
10.1039/b506199g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Self assembly of the ditopic ligand L-1 with Cu2+ gives the dinuclear double helicate [Cu-2(L-1)(2)](4+), which can further coordinate s-block cations. This coordination alters the helicate pitch to a variety of different lengths depending on the size and charge of the guest cation.
引用
收藏
页码:4158 / 4160
页数:3
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