First alpha,beta-unsaturated mononuclear bisylidene complex of tungsten: Synthesis and structure

被引：10

作者：

Barluenga, J ^{[1
]}

Aznar, F ^{[1
]}

Weyershausen, B ^{[1
]}

GarciaGranda, S ^{[1
]}

Martin, E ^{[1
]}

机构：

[1] UNIV OVIEDO,DEPT QUIM FIS & ANALIT,OVIEDO 33071,SPAIN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 21期

关键词：

D O I：

10.1039/cc9960002455

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

cis-Tetracarbonyl [(1-cyclopentenyl)(N-morpholino)methylidene](2-hydroxyphenyl isocyano)tungsten(0) 5 undergoes intramolecular cyclization by deprotonation and subsequent N-alkylation to give the novel bisylidene complex 6, which is characterized by a single-crystal X-ray structure analysis.

引用

页码：2455 / 2456

页数：2

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