Electrocatalytic reduction of CO2 to CO by polypyridyl ruthenium complexes

被引：202

作者：

Chen, Zuofeng ^{[1
]}

Chen, Chuncheng ^{[1
]}

Weinberg, David R. ^{[1
]}

Kang, Peng ^{[1
]}

Concepcion, Javier J. ^{[1
]}

Harrison, Daniel P. ^{[1
]}

Brookhart, Maurice S. ^{[1
]}

Meyer, Thomas J. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 47期

关键词：

CARBON-DIOXIDE; ELECTROCHEMICAL REDUCTION; WATER; BOND;

D O I：

10.1039/c1cc15071e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrocatalytic reduction of CO2 by [Ru(tpy)(bpy)(solvent)](2+) (tpy = 2,2':6',2 ''- terpyridine, bpy = 2,2'-bipyridine) and its structural analogs is initiated by sequential 1e(-) reductions at the tpy and bpy ligands followed by rate limiting CO2 addition to give a metallocarboxylate intermediate. It undergoes further reduction and loss of CO.

引用

页码：12607 / 12609

页数：3

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