Rapid transfer of hydride ion from a ruthenium complex to C1 species in water

被引：71

作者：

Creutz, Carol ^{[1
]}

Chou, Mei H. ^{[1
]}

机构：

[1] Brookhaven Natl Lab, Dept Chem, Upton, NY 11973 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 33期

关键词：

D O I：

10.1021/ja074158w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solvent water (Gutmann acceptor number, AN = 55) accelerates the rate of reaction of Ru(terpy)(bpy)H+ with CO2 by more than 4 orders of magnitude compared to acetonitrile (AN 18.9) (as reported in Inorg. Chim. Acta 2000, 299, 155). Water also promotes the related reductions of carbon monoxide to formaldehyde and of formaldehyde to methanol by the ruthenium(II) hydride complex.

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页码：10108 / +

页数：3

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