Plant oils: The perfect renewable resource for polymer science?!

被引：491

作者：

de Espinosa, Lucas Montero ^{[1
]}

Meier, Michael A. R. ^{[1
]}

机构：

[1] Karlsruhe Inst Technol, Inst Organ Chem, D-76131 Karlsruhe, Germany

来源：

EUROPEAN POLYMER JOURNAL | 2011年 / 47卷 / 05期

关键词：

Plant oils; Fatty acids; Metathesis; ADMET; Thiol-ene; Monomer synthesis; OPENING METATHESIS POLYMERIZATION; FATTY-ACID DERIVATIVES; IONIC-COORDINATIVE POLYMERIZATION; FREE-RADICAL COPOLYMERIZATION; FLAME-RETARDANT POLYMERS; ACYCLIC DIENE METATHESIS; CONJUGATED LINSEED OIL; ENE CLICK REACTIONS; SOYBEAN-OIL; CROSS-METATHESIS;

D O I：

10.1016/j.eurpolymj.2010.11.020

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Already for a long time, plant oils and their derivatives have been used by polymer chemists due to their renewable nature, world wide availability, relatively low price, and their rich application possibilities. Although many different synthetic approaches have been used, more recent examples are pointing in the direction of catalytic transformations and other efficient reactions to achieve a more sustainable production of polymers from these renewable resources. In this context, olefin metathesis, thiol-ene additions, and other processes can contribute not only to a more efficient synthesis of plant oil based polymers, but also to broaden the application possibilities of plant oils. This feature article provides an overview of the present situation with special attention to the use of olefin metathesis and thiol-ene chemistry as synthetic methods and as polymerization techniques. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：837 / 852

页数：16

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