Diastereoisomerically selective enantiomerically pure titanium complexes of Salan ligands: Synthesis, structure, and preliminary activity studies

被引：72

作者：

Yeori, A ^{[1
]}

Groysman, S ^{[1
]}

Goldberg, I ^{[1
]}

Kol, M ^{[1
]}

机构：

[1] Tel Aviv Univ, Sch Chem, Raymond & Beverly Sackler Fac Exact Sci, IL-69978 Tel Aviv, Israel

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 13期

关键词：

D O I：

10.1021/ic050745b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The degree of diastereoselectivity in the wrapping of four new chiral Salan ligands to form chiral-at-metal titanium complexes ranged from mild to perfect as a function of the ligands' N substituents; the enantiomerically pure complexes catalyzed the addition of diethyl zinc to benzaldehyde in 73-76% enantiomeric excess.

引用

页码：4466 / 4468

页数：3

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