Characterization and antimicrobial properties of fluorine-rich carbon films deposited on poly(lactic acid)

被引：15

作者：

Boonyawan, D. ^{[1
,2
]}

Sarapirom, S. ^{[1
,2
]}

Tunma, S. ^{[1
,2
]}

Chaiwong, C. ^{[1
,2
]}

Rachtanapun, P. ^{[3
]}

Auras, R. ^{[4
]}

机构：

[1] Chiang Mai Univ, Fac Sci, Dept Phys & Mat Sci, Plasma & Beam Phys Res Facil, Chiang Mai 50200, Thailand

[2] Thailand Ctr Excellence Phys, CHE, Bangkok 10400, Thailand

[3] Chiang Mai Univ, Fac Agroind, Div Packaging Technol, Chiang Mai 50100, Thailand

[4] Michigan State Univ, Sch Packaging, E Lansing, MI 48824 USA

来源：

SURFACE & COATINGS TECHNOLOGY | 2011年 / 205卷

关键词：

Fluorine-rich carbon film; Poly(lactic acid); Escherichia coli (E. coli); BLENDS;

D O I：

10.1016/j.surfcoat.2011.03.095

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

This study describes the effect of fluorine contents on the properties of carbon films deposited on poly(lactic acid) (PLA) substrate using plasma enhanced chemical vapor deposition (PECVD) technique. A mixture of acetylene (C2H2) and carbon tetrafluoride (CF4) gas was utilized for film deposition. The thickness of the deposited carbon film was in the range of 150-350 nm. The film's deposition rate was found to increase with the decreasing CF4 concentration in the gas mixture. Fourier transform spectroscopy revealed the presence of C-F bonds, and X-ray photoelectron spectroscopy showed that the C-C bonds of the carbon film were replaced by the C-CFx bonds. This affirms that the films have a polymer-like structure. High concentration of fluorine (up to 25 at.%) could be obtained when 50% of CF4, was used. PLA coated with F-rich carbon film showed hydrophobic character due to the formation of -CFx bonds. The film with a high concentration of fluorine showed excellent performance on reduction of Escherichia coli (E. coli) growth. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：S552 / S557

页数：6

共 23 条

[1] Structural and chemical characterization of fluorinated amorphous carbon films (a-C:F) as a liquid crystal alignment layer [J].

Ahn, Han Jin ;

Kim, Jong Bok ;

Hwang, Byoung Har ;

Baik, Hong Koo ;

Park, Jin Seoul ;

Kang, Daeseung .

[2]

ALMENAR E, 2007, 23 IAPRI S PACK IAPR

[3] The properties of fluorine containing diamond-like carbon films prepared by plasma-enhanced chemical vapour deposition [J].

Bendavid, A. ;

Martin, P. J. ;

Randeniya, L. ;

Amin, M. S. .

[4] Effect of plasma treatment on hydrophobicity and barrier property of polylactic acid [J].

Chaiwong, C. ;

Rachtanapun, P. ;

Wongchaiya, P. ;

Auras, R. ;

Boonyawan, D. .

SURFACE & COATINGS TECHNOLOGY, 2010, 204 (18-19) :2933-2939

[5] Polymersomes [J].

Discher, Dennis E. ;

Ahmed, Fariyal .

ANNUAL REVIEW OF BIOMEDICAL ENGINEERING, 2006, 8 :323-341

[6] Surface analysis and bioreactions of F and Si containing a-C:H [J].

Hauert, R ;

Muller, U ;

Francz, G ;

Birchler, F ;

Schroeder, A ;

Mayer, J ;

Wintermantel, E .

THIN SOLID FILMS, 1997, 308 :191-194

[7]

Ikada Y, 2000, MACROMOL RAPID COMM, V21, P117, DOI 10.1002/(SICI)1521-3927(20000201)21:3<117::AID-MARC117>3.0.CO

[8]

2-X

[9] Antibacterial activity of fluorine incorporated DLC films [J].

Ishihara, M. ;

Kosaka, T. ;

Nakamura, T. ;

Tsugawa, K. ;

Hasegawa, M. ;

Kokai, F. ;

Koga, Y. .

[10] Fluorine incorporated amorphous carbon thin films prepared by Surface Wave Microwave Plasma CVD [J].

Kalita, Golap ;

Aryal, Hare Ram ;

Adhikar, Sudip ;

Ghimire, Dilip C. ;

Afre, Rakesh A. ;

Soga, Tetsuo ;

Sharon, Maheshwar ;

Umeno, Masayoshi .

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