Mechanical and optical properties of hard SiCN coatings prepared by PECVD

Novel amorphous SiCN coatings are becoming increasingly attractive because of their mechanical, optical and electronic properties. In the present work, SiCN films were fabricated by PECVD from SiH4/CH4/N-2/Ar gas mixtures at a temperature of 400 degreesC. Mechanical properties such as hardness, Young's modulus, friction coefficient and stress were evaluated, respectively, by depth-sensing indentation, pin-on-disk, micro-scratch and curvature methods. Films deposited under optimized conditions exhibited a hardness > 30 GPa, Young's modulus > 190 GPa, elastic rebound of 85% and a compressive stress of approximately I GPa. A friction coefficient against Al2O3, ranging from 0.75 to 0.25 and a low surface roughness of approximately 1 nm were found to be accompanied by a refractive index ranging from 1.85 to 2.10 (at 550 nm) and an extinction coefficient between 1.0 X 10(-4) and 4.5 X 10(-2). The film behavior is correlated with the microstructure and composition determined by SEM, XPS, AFM and broad-range UV-VIS-NIR-IR spectroscopic ellipsometry. (C) 2003 Elsevier B.V. All rights reserved.