Asymmetric oxyselenenylation-deselenenylation reactions of alkenes induced by camphor diselenide and ammonium persulfate. A convenient one-pot synthesis of enantiomerically enriched allylic alcohols and ethers

被引：42

作者：

Tiecco, M ^{[1
]}

Testaferri, L ^{[1
]}

Marini, F ^{[1
]}

Santi, C ^{[1
]}

Bagnoli, L ^{[1
]}

Temperini, A ^{[1
]}

机构：

[1] Univ Perugia, Fac Farm, Ist Chim Organ, I-06123 Perugia, Italy

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 04期

关键词：

D O I：

10.1016/S0957-4166(99)00048-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of beta,gamma-unsaturated esters and nitriles with camphor diselenide and ammonium persulfate in methanol, ethylene glycol or water affords enantiomerically enriched gamma-alkoxy or gamma-hydroxy alpha,beta-unsaturated derivatives, respectively, in good chemical yields and with moderate to good enantioselectivity. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：747 / 757

页数：11

共 29 条

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