LiBH4 nanoparticles supported by disordered mesoporous carbon:: Hydrogen storage performances and destabilization mechanisms

被引：125

作者：

Zhang, Yao ^{[1
]}

Zhang, Wan-Sheng

Wang, Ai-Qin

Sun, Li-Xian

Fan, Mei-Qiang

Chu, Hai-Liang

Sun, Jun-Cai

Zhang, Tao

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China

[2] Dalian Maritime Univ, Electromech & Mat Engn Coll, Dalian 116026, Peoples R China

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2007年 / 32卷 / 16期

关键词：

LiBH4; nanoparticles; disordered mesoporous carbon; hydrogen storage performances; destabilization mechanisms;

D O I：

10.1016/j.ijhydene.2007.04.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

LiBH4 nanoparticles supported by disordered mesoporous carbon CMK-3, denoted as nano-LiBH4/C-mesoporous, were synthesized in the present work. Nano-LiBH4 in this sample was destabilized significantly, resulting in more favorable latent heat of dehydrogenation (40 kJ/mol H-2), large amount of dehydrogenation capacity (14wt%) below 600 degrees C and reversible capacity of 6.0wt% H-2 at 350 degrees C. It was revealed that such destabilization results from two kinds of mechanisms: nano-dispersion and reaction with mesoporous carbon. Both mechanisms exert synergistic effects on the dehydrogenation of nano-LiBH4 and reverse hydrogenation. (c) 2007 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

引用

页码：3976 / 3980

页数：5

共 23 条

[1] Modified lithium borohydrides for reversible hydrogen storage
An, M
Jurgensen, A
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (13) : 7062 - 7067
[2] Destabilization of LiBH4 by mixing with LiNH2
Aoki, M
Miwa, K
Noritake, T
Kitahara, G
Nakamori, Y
Orimo, S
Towata, S
[J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2005, 80 (07): : 1409 - 1412
[3] Facilitated hydrogen storage in NaAlH4 supported on carbon nanoribers
Balde, Cornelis P.
Hereijgers, Bart P. C.
Bitter, Johannes H.
de Jong, Krijn P.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (21) : 3501 - 3503
[4] Ti-doped alkali metal aluminium hydrides as potential novel reversible hydrogen storage materials
Bogdanovic, B
Schwickardi, M
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 253 (1-2) : 1 - 9
[5] Interaction of hydrogen with metal nitrides and imides
Chen, P
Xiong, ZT
Luo, JZ
Lin, JY
Tan, KL
[J]. NATURE, 2002, 420 (6913) : 302 - 304
[6] Raman studies of reorientation motions of [BH4]- anionsin alkali borohydrides
Hagemann, H
Gomes, S
Renaudin, G
Yvon, K
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 363 (1-2) : 126 - 129
[7] Rechargeable hydrogen storage in nanostructured mixtures of hydrogenated carbon and lithium hydride
Ichikawa, T
Fujii, H
Isobe, S
Nabeta, K
[J]. APPLIED PHYSICS LETTERS, 2005, 86 (24) : 1 - 3
[8] Chemical activation of MgH2;: a new route to superior hydrogen storage materials
Johnson, SR
Anderson, PA
Edwards, PP
Gameson, I
Prendergast, JW
Al-Mamouri, M
Book, D
Harris, IR
Speight, JD
Walton, A
[J]. CHEMICAL COMMUNICATIONS, 2005, (22) : 2823 - 2825
[9] Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure
Jun, S
Joo, SH
Ryoo, R
Kruk, M
Jaroniec, M
Liu, Z
Ohsuna, T
Terasaki, O
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (43) : 10712 - 10713
[10] Hydrogen release from mixtures of lithium borohydride and lithium amide: A phase diagram study
Meisner, GP
Scullin, ML
Balogh, MP
Pinkerton, FE
Meyer, MS
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (09) : 4186 - 4192

← 1 2 3 →