The role of donor group orientation as a factor in metal ion recognition by ligands

被引：130

作者：

Hay, BP

Hancock, RD

机构：

[1] Pacific NW Natl Lab, Richland, WA 99352 USA

[2] Power Engn, Provo, UT 84602 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2001年 / 212卷

关键词：

molecular mechanics; metal ions; ligand design; amine; ether; complementarity preorganisation; amide;

D O I：

10.1016/S0010-8545(00)00366-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Factors that control the metal ion complementarity of ligand architectures are described. These include cavity size, metal ion topography, and donor group orientation. Attention focuses on the last factor with a detailed discussion of how molecular mechanics has been used to investigate the role of donor group orientation in polyamine and polyether ligands, (C) 2001 Elsevier Science B.V, All rights reserved.

引用

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页码：61 / 78

页数：18

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