Recent developments in cyclization reactions of α-aminoalkyl radicals

被引：49

作者：

Aurrecoechea, JM ^{[1
]}

Suero, R ^{[1
]}

机构：

[1] Univ Basque Country, Fac Ciencias & Tecnol, Dept Quim Inorgan 2, Apartado 644, E-48080 Bilbao, Spain

来源：

ARKIVOC | 2004年

关键词：

alpha-aminoalkyl radical; intramolecular radical additions; pyrrolidines; homolytic cleavage; translocation; PET; SmI2-promoted reductions;

D O I：

10.3998/ark.5550190.0005.e02

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The intramolecular additions of C-centered neutral alpha-aminoalkyl radicals onto suitably positioned C-C double bonds provide a ready access into functionalized carbocycles and heterocycles. This strategy offers considerable versatility in the selection of starting materials since a number of methods using different functional groups and reagents are available for Phi-aminoalkyl radical generation. This review covers the recent progress in this field.

引用

页码：10 / 35

页数：26

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