Evidence for the net addition of arene C-H bonds across a Ru(II)-hydroxide bond

被引：108

作者：

Feng, Y

Lail, M

Barakat, KA

Cundari, TR

Gunnoe, TB ^{[1
]}

Petersen, JL

机构：

[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

[2] Univ N Texas, Dept Chem, Denton, TX 76203 USA

[3] W Virginia Univ, C Eugene Bennett Dept Chem, Morgantown, WV 26506 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 41期

关键词：

D O I：

10.1021/ja054101e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

TpRu(PMe3)2(OH) (1) reacts with C6D6 to initiate H/D exchange between the hydroxide ligand and the deuterated benzene. In addition, complex 1 catalyzes H/D exchange between H2O and C6D6. Mechanistic and computational studies suggest that a likely reaction pathway for the H/D exchange involves loss of PMe3 to produce {TpRu(PMe3)(OH)}, followed by the net addition of a benzene C-H(D) bond across the Ru-OH bond to form the putative complex TpRu(PMe3)(OH2)(Ph). Copyright © 2005 American Chemical Society.

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页码：14174 / 14175

页数：2

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