Enantioselective palladium catalyzed allylic substitution with sulfur-containing pyridine ligands

被引：69

作者：

Chelucci, G

Cabras, MA

机构：

[1] Dipartimento di Chimica, Università di Sassari, I-07100 Sassari

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 04期

关键词：

D O I：

10.1016/0957-4166(96)00092-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diastereomerically pure (5R,7R,8S)- and (5R,7R,8R)-5,6,7,8-tetrahydro-6, 6-dimethyl-2-phenyl-8-phenyltio-5,7-methanoquinoline were prepared and assessed in the enantioselective palladium catalyzed allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethylmalonate. Enantioselectivities up to 83% were obtained. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：965 / 966

页数：2

共 16 条

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