Ag-enhanced SEI formation on Si particles for lithium batteries

被引：110

作者：

Wu, XD ^{[1
]}

Wang, ZX ^{[1
]}

Chen, LQ ^{[1
]}

Huang, XJ ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Phys, Nanoscale Phys & Device Lab, Beijing 100080, Peoples R China

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2003年 / 5卷 / 11期

基金：

中国国家自然科学基金; 美国国家科学基金会;

关键词：

Si; anode; Li-ion batteries; Ag-deposition;

D O I：

10.1016/j.elecom.2003.09.001

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Ag particles have been deposited on commercial Si particles. The effects of Ag deposition on Si are characterized with scanning electron microscopy (SEM), XPS, XRD, CV, LSC and EIS. The improved electrochemical performance of Si electrode is attributed to the decomposition of electrolyte on Ag/Si electrode prior to Li insertion that leads to Si particle pulverization. The products of the decomposed electrolyte binds the Si particles and ensures good electric contact between them. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：935 / 939

页数：5

共 22 条

[1] Single-electrode Peltier heats of Li-Si alloy electrodes in LiCl-KCl eutectic melt
Amezawa, K
Yamamoto, N
Tomii, Y
Ito, Y
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (06) : 1986 - 1993
[2] MULTINARY ALLOY ELECTRODES FOR SOLID-STATE BATTERIES .2. A NEW LI-SI-MG ALLOY NEGATIVE ELECTRODE MATERIAL FOR USE IN HIGH-ENERGY DENSITY RECHARGEABLE LITHIUM CELLS
ANANI, A
HUGGINS, RA
[J]. JOURNAL OF POWER SOURCES, 1992, 38 (03) : 363 - 372
[3] Colossal reversible volume changes in lithium alloys
Beaulieu, LY
Eberman, KW
Turner, RL
Krause, LJ
Dahn, JR
[J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (09) : A137 - A140
[4] Thin-film crystalline SnO2-lithium electrodes
Brousse, T
Retoux, R
Herterich, U
Schleich, DM
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (01) : 1 - 4
[5] Carbon-coated silicon as anode material for lithium ion batteries: advantages and limitations
Dimov, N
Kugino, S
Yoshio, M
[J]. ELECTROCHIMICA ACTA, 2003, 48 (11) : 1579 - 1587
[6] Structured silicon anodes for lithium battery applications
Green, M
Fielder, E
Scrosati, B
Wachtler, M
Serra Moreno, J
[J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (05) : A75 - A79
[7] Amorphous silicon thin-film negative electrode prepared by low pressure chemical vapor deposition for lithium-ion batteries
Jung, HJ
Park, M
Han, SH
Lim, H
Joo, SK
[J]. SOLID STATE COMMUNICATIONS, 2003, 125 (7-8) : 387 - 390
[8] Nanostructured Si/TiB2 composite anodes for Li-ion batteries
Kim, I
Blomgren, GE
Kumta, PN
[J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (08) : A157 - A161
[9] Fe/Si multi-layer thin film anodes for lithium rechargeable thin film batteries
Kim, JB
Lee, HY
Lee, KS
Lim, SH
Lee, SM
[J]. ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (07) : 544 - 548
[10] Si-Zr alloy thin-film anodes for microbatteries
Lee, SJ
Lee, HY
Baik, HK
Lee, SM
[J]. JOURNAL OF POWER SOURCES, 2003, 119 : 113 - 116

← 1 2 3 →