Stereospecific synthesis of β-D-allopyrano sides by dihydroxylation of β-D-erythro-2,3-dideoxyhex-2-enopyranosides

被引：19

作者：

Murphy, PV ^{[1
]}

O'Brien, JL

Smith, AB

机构：

[1] Natl Univ Ireland Univ Coll Dublin, Dept Chem, Conway Inst Biomol & Biomed Res, Dublin 4, Ireland

[2] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA

来源：

CARBOHYDRATE RESEARCH | 2001年 / 334卷 / 04期

关键词：

stereospecific synthesis; beta-D-allopyranoside; dihydroxylation; beta-D-erythro-2,3-Dideoxyhex-2-enopyrano sides; inversion of configuration;

D O I：

10.1016/S0008-6215(01)00181-1

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The synthesis of 4,6-O-benzylidene-beta -D-erythro-2-3-dideoxyhex-2-enopyranosides and their osmium and ruthenium catalysed dihydroxylation reactions have been investigated. These reactions have been shown, for a range of monosaccharides and a disaccharide, to proceed stereospecifically to give beta -D-allopyranosides in moderate to excellent yield. (C) 2001 Published by Elsevier Science Ltd.

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收藏

页码：327 / 335

页数：9

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