Multiwalled carbon nanotubes grown in hydrogen atmosphere: An x-ray diffraction study

被引:104
作者
Maniwa, Y
Fujiwara, R
Kira, H
Tou, H
Nishibori, E
Takata, M
Sakata, M
Fujiwara, A
Zhao, XL
Iijima, S
Ando, Y
机构
[1] Tokyo Metropolitan Univ, Dept Phys, Tokyo 1920397, Japan
[2] Nagoya Univ, Dept Appl Phys, Nagoya, Aichi 4648603, Japan
[3] Univ Tokyo, Sch Sci, Dept Phys, Bunkyo Ku, Tokyo 113, Japan
[4] JST, ICORP, Nanotubulite Project, Tokyo, Japan
[5] Meijyo Univ, Dept Mat Sci & Engn, Tempaku Ku, Nagoya, Aichi 4688502, Japan
关键词
D O I
10.1103/PhysRevB.64.073105
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
X-ray diffraction study of multiwalled carbon nanotube (MWNT) grown by are discharge in hydrogen atmosphere is presented. It is found that the thermal-expansion coefficient along the radial direction of MWNT is widely distributed in a range from 1.6 x 10(-5) K-1 to 2.6 x 10(-5) K-1, indicating the existence of both of Russian doll MWNT and highly defective MWNT. Russian doll MWNT is suggested to have the outer diameter less than similar to 100 Angstrom. Thicker MWNT's are typically highly defective, and may have the jelly roll (scroll) or defective polygonal structure consisting of flat graphite domains.
引用
收藏
页码:731051 / 731054
页数:4
相关论文
共 21 条
[1]   A STRUCTURE MODEL AND GROWTH-MECHANISM FOR MULTISHELL CARBON NANOTUBES [J].
AMELINCKX, S ;
BERNAERTS, D ;
ZHANG, XB ;
VANTENDELOO, G ;
VANLANDUYT, J .
SCIENCE, 1995, 267 (5202) :1334-1338
[2]   Radial thermal expansion of purified multiwall carbon nanotubes measured by X-ray diffraction [J].
Bandow, S .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1997, 36 (10B) :L1403-L1405
[3]   COBALT-CATALYZED GROWTH OF CARBON NANOTUBES WITH SINGLE-ATOMIC-LAYERWALLS [J].
BETHUNE, DS ;
KIANG, CH ;
DEVRIES, MS ;
GORMAN, G ;
SAVOY, R ;
VAZQUEZ, J ;
BEYERS, R .
NATURE, 1993, 363 (6430) :605-607
[4]  
DRESSELHAUS MS, 1995, SCI FULLERLENES CARB
[5]   Graphite polyhedral crystals [J].
Gogotsi, Y ;
Libera, JA ;
Kalashnikov, N ;
Yoshimura, M .
SCIENCE, 2000, 290 (5490) :317-320
[6]  
Harris P.J.F., 1999, Carbon Nanotubes and Related Structures, DOI DOI 10.1017/CBO9780511605819
[7]   SINGLE-SHELL CARBON NANOTUBES OF 1-NM DIAMETER [J].
IIJIMA, S ;
ICHIHASHI, T .
NATURE, 1993, 363 (6430) :603-605
[8]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[9]  
KATAURA H, 2001, MRS P, V593, P113
[10]   Size effects in carbon nanotubes [J].
Kiang, CH ;
Endo, M ;
Ajayan, PM ;
Dresselhaus, G ;
Dresselhaus, MS .
PHYSICAL REVIEW LETTERS, 1998, 81 (09) :1869-1872