Development of chemo-, regio-, and enantioselective [2+2+2] cycloadditions catalyzed by cationic Rhodium(I)/BINAP-type bisphosphine complexes

被引：16

作者：

Tanaka, Ken ^{[1
]}

Nishida, Goushi ^{[1
]}

Suda, Takeshi ^{[1
]}

机构：

[1] Tokyo Univ Agr & Technol, Grad Sch Engn, Dept Appl Chem, Koganei, Tokyo 1848588, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2007年 / 65卷 / 09期

关键词：

alkynes; asymmetric catalysis; biaryls; BINAP; cycloadditions; cyclophanes; heterocycles; phosphines; rhodium; spiranes; AXIALLY CHIRAL BIARYLS; ONE-STEP SYNTHESIS; TERMINAL ALKYNES; INTERMOLECULAR CYCLOTRIMERIZATION; CROSS-CYCLOTRIMERIZATION; ASYMMETRIC-SYNTHESIS; KINETIC RESOLUTION; ALLYLIC ALCOHOLS; MILD CONDITIONS; RHODIUM;

D O I：

10.5059/yukigoseikyokaishi.65.862

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Our research group first demonstrated that cationic rhodium(l) complexes with BINAP-type bisphosphine ligands are versatile new catalysts for highly chemo-, regio-, and enantioselective [2 + 2 + 2] cycloadditions. Highly efficient catalytic synthesis of substituted benzenes, cyclophanes, and nitrogen heterocycles was achieved with high chemo- and regioselectivity using these catalysts. Enantio selective variants of these cycloadditions were also developed, which realized efficient catalytic constructions of axial, planar, and central chirality.

引用

页码：862 / 873

页数：12

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