A second look at polythieno[3,4-b]pyrazines:: Chemical vs electrochemical polymerization and its effect on band gap

被引：42

作者：

Kenning, DD ^{[1
]}

Rasmussen, SC ^{[1
]}

机构：

[1] N Dakota State Univ, Dept Chem, Fargo, ND 58105 USA

来源：

MACROMOLECULES | 2003年 / 36卷 / 17期

关键词：

D O I：

10.1021/ma034831b

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Highly conjugated materials with very low band gaps were produced via electropolymerization, provided steps were taken to limit overoxidation. In contrast, it was shown that the metal-binding ability of pTPs makes polymerization via FeCl3 problematic.

引用

页码：6298 / 6299

页数：2

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