Highly selective hydrocyanation of butadiene toward 3-pentenenitrile

被引：96

作者：

Bini, Laura

Mueller, Christian

Wilting, Jos

von Chrzanowski, Lars

Spek, Anthony L.

Vogt, Dieter ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 42期

关键词：

D O I：

10.1021/ja074922e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A triptycene-based diphosphine ligand was synthesized in good yield following a new route. The corresponding Pt(II)- and Ni(0)complexes were characterized. In butadiene hydrocyanation the tript-PPh2Ni(cod) catalyst leads to exceptionally high selectivities for the linear product 3-pentenenitrile, combining high activity for both hydrocyanation and isomerization. This one-step procedure could be the key toward process intensification.

引用

页码：12622 / +

页数：3

共 26 条

[1] Nickel complexes involved in the isomerization of 2-methyl-3-butenenitrile
Acosta-Ramirez, Alberto
Flores-Gaspar, Areli
Munoz-Hernandez, Miguel
Arevalo, Alma
Jones, William D.
Garcia, Juventino J.
[J]. ORGANOMETALLICS, 2007, 26 (07) : 1712 - 1720
[2] Isomerization of 2-methyl-3-butenenitrile with (bis-diphenylphosphinoferrocene)nickel compounds:: Catalytic and structural studies
Acosta-Ramirez, Alberto
Munoz-Hernandez, Miguel
Jones, William D.
Garcia, Juventino J.
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (18) : 3895 - 3901
[3] AHLERS W, 2001, Patent No. 01058589
[4] Ahlers W., 2002, [No title captured], Patent No. [WO 02/083695A1, 02083695]
[5] Rigid trans-spanning triptycene-based ligands:: How flexible they can be?
Azerraf, Clarite
Grossman, Olga
Gelman, Dmitri
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (04) : 761 - 767
[6] Roof-shaped halide-bridged bimetallic complexes via ring expansion reaction
Azerraf, Clarite
Cohen, Shmuel
Gelman, Dmitri
[J]. INORGANIC CHEMISTRY, 2006, 45 (17) : 7010 - 7017
[7] CHELATING DIPHOSPHITE COMPLEXES OF NICKEL(0) AND PLATINUM(0) - THEIR REMARKABLE STABILITY AND HYDROCYANATION ACTIVITY
BAKER, MJ
HARRISON, KN
ORPEN, AG
PRINGLE, PG
SHAW, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (12) : 803 - 804
[8] CHIRAL ARYL DIPHOSPHITES - A NEW CLASS OF LIGANDS FOR HYDROCYANATION CATALYSIS
BAKER, MJ
PRINGLE, PG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (18) : 1292 - 1293
[9] LIGAND ELECTRONIC EFFECTS IN ASYMMETRIC CATALYSIS - ENHANCED ENANTIOSELECTIVITY IN THE ASYMMETRIC HYDROCYANATION OF VINYLARENES
CASALNUOVO, AL
RAJANBABU, TV
AYERS, TA
WARREN, TH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (22) : 9869 - 9882
[10] Catalytic isomerization of cyanoolefins involved in the adiponitrile process.: C-CN bond cleavage and structure of the nickel π-allyl cyanide complex Ni(η3-1-Me-C3H4)(CN)(dppb)
Chaumonnot, A
Lamy, F
Sabo-Etienne, S
Donnadieu, B
Chaudret, B
Barthelat, JC
Galland, JC
[J]. ORGANOMETALLICS, 2004, 23 (14) : 3363 - 3365

← 1 2 3 →