Highly selective hydrocyanation of butadiene toward 3-pentenenitrile

被引：96

作者：

Bini, Laura

Mueller, Christian

Wilting, Jos

von Chrzanowski, Lars

Spek, Anthony L.

Vogt, Dieter ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 42期

关键词：

D O I：

10.1021/ja074922e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A triptycene-based diphosphine ligand was synthesized in good yield following a new route. The corresponding Pt(II)- and Ni(0)complexes were characterized. In butadiene hydrocyanation the tript-PPh2Ni(cod) catalyst leads to exceptionally high selectivities for the linear product 3-pentenenitrile, combining high activity for both hydrocyanation and isomerization. This one-step procedure could be the key toward process intensification.

引用

页码：12622 / +

页数：3

共 26 条

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