Rhodium wires based on binuclear acetate-bridged complexes

被引：49

作者：

Pruchnik, FP

Jakimowicz, P

Ciunik, Z

Stanislawek, K

Oro, LA

Tejel, C

Ciriano, MA

机构：

[1] Wroclaw B Beirut Univ, Fac Chem, PL-50383 Wroclaw, Poland

[2] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Dept Quim Inorgan, E-5009 Zaragoza, Spain

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 01期

关键词：

metal wires; nitrogen heterocycles; N ligands; rhodium; stacking interactions;

D O I：

10.1016/S1387-7003(00)00183-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, properties, structure and conductivity of a new class of one-dimensional, mixed valence Rh(I)-Rh(II) complexes {Rh-2(mu -O2CMe)(2)(N-N)(2)][BX4]}(n) (N-N = bipyridine, phenanthroline; X = F, Ph) are described. (C) 2001 Published by Elsevier Science B.V. All rights reserved.

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页码：19 / 22

页数：4

相关论文

共 22 条

[1]

[Anonymous], 1987, INTRO SYNTHETIC ELEC

[2] Triazenide-bridged dirhodium complexes containing redox-active cyanomanganese ligands [J].

Bardaji, M ;

Brown, NC ;

Christofides, A ;

Connelly, NG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (12) :2511-2518

[3] Studies of antibacterial activity of binuclear rhodium(II) complexes with heterocyclic nitrogen ligands [J].

Bien, M ;

Pruchnik, FP ;

Seniuk, A ;

Lachowicz, TM ;

Jakimowicz, P .

JOURNAL OF INORGANIC BIOCHEMISTRY, 1999, 73 (1-2) :49-55

[4] ELECTRONIC-STRUCTURE OF LIGAND-BRIDGED COMPLEXES CONTAINING THE [RH2[3+ CORE - ESR SPECTROSCOPY, MO CALCULATIONS, AND X-RAY STRUCTURES OF THE 3 REDOX PAIRS [RH2(CO)2LL'(MU-PHNC(ME)NPH)2]Z [Z=0,1 L=L'=PPH3, P(OPH)3 - L=PPH3, L'=P (OPH)3] [J].

BOYD, DC ;

CONNELLY, NG ;

HERBOSA, GG ;

HILL, MG ;

MANN, KR ;

MEALLI, C ;

ORPEN, AG ;

RICHARDSON, KE ;

RIEGER, PH .

INORGANIC CHEMISTRY, 1994, 33 (05) :960-971

[5] UNIQUE ECLIPSED COFACIAL OLIGOMERIC COMPLEXES OF RHODIUM CONTAINING 3-LAYERED BONDING OF 9,10-PHENANTHROQUINONEDIIMINE [J].

CHERN, SS ;

LEE, GH ;

PENG, SM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (14) :1645-1646

[6] Studies of tetrakis(trifluoroacetate) dirhodium -: Part 4.: Solventless synthesis of Rh2(O2CCF3)2(CO)4 combined with Rh2(O2CCF3)4, a compound with infinite chains of rhodium atoms [J].

Cotton, FA ;

Dikarev, EV ;

Petrukhina, MA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 596 (1-2) :130-135

[7] Reaction of nitrogen chelates with the [Rh-2](4+) core: Bis-chelate products and demonstration of reversible, chelate-based reduction processes [J].

Crawford, CA ;

Matonic, JH ;

Huffman, JC ;

Folting, K ;

Dunbar, KR ;

Christou, G .

INORGANIC CHEMISTRY, 1997, 36 (11) :2361-2371

[8] STRUCTURAL, CONDUCTIVITY AND SPECTROSCOPIC ASPECTS OF ONE-DIMENSIONAL TRANSITION-METAL COMPLEXES [J].

FERRARO, JR .

COORDINATION CHEMISTRY REVIEWS, 1982, 43 (MAY) :205-232

[9] Structure and properties of di-μ-acetato-dichlorobis(2,2′-bipyridine)dirhodium(II)-trihydrate [J].

Galdecka, E ;

Galdecki, Z ;

Pruchnik, FP ;

Jakimowicz, P .

TRANSITION METAL CHEMISTRY, 2000, 25 (03) :315-319

[10] PLANAR COMPLEXES CONTAINING METAL-METAL BONDS [J].

KROGMANN, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1969, 8 (01) :35-&