The first example or polymer-supported palladium catalyst for stereoselective S-S bond addition to terminal alkynes

被引:51
作者
Ananikov, VP
Kabeshov, MA
Beletskaya, IP
机构
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
关键词
palladium complexes; polymer-supported; catalysis; vinyl sulphides;
D O I
10.1055/s-2005-865195
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The polymer-supported recyclable palladium catalyst was prepared for stereoselective diaryl disulphides addition to terminal alkynes with high yields. The 96-98% product purity was achieved after filtering thic polymer-supported catalyst without special purification procedure.
引用
收藏
页码:1015 / 1017
页数:3
相关论文
共 19 条
[1]   Palladium-catalyzed addition of disulfides and diselenides to alkynes under solvent free conditions [J].
Ananikov, VP ;
Beletskaya, IP .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2004, 2 (03) :284-287
[2]   Mechanistic study of palladium catalyzed S-S and Se-Se bonds addition to alkynes [J].
Ananikov, VP ;
Kabeshov, MA ;
Beletskaya, IP ;
Aleksandrov, GG ;
Eremenko, IL .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 687 (02) :451-461
[3]   Mechanistic investigation and new catalyst design in palladium- and platinum-catalyzed Se-Se bond addition to alkynes [J].
Ananikov, VP ;
Beletskaya, IP ;
Aleksandrov, GG ;
Eremenko, IL .
ORGANOMETALLICS, 2003, 22 (07) :1414-1421
[4]   Origins, current status, and future challenges of green chemistry [J].
Anastas, PT ;
Kirchhoff, MM .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :686-694
[5]   Catalysis as a foundational pillar of green chemistry [J].
Anastas, PT ;
Kirchhoff, MM ;
Williamson, TC .
APPLIED CATALYSIS A-GENERAL, 2001, 221 (1-2) :3-13
[6]   Element-element addition to alkynes catalyzed by the group 10 metals [J].
Beletskaya, I ;
Moberg, C .
CHEMICAL REVIEWS, 1999, 99 (12) :3435-3461
[7]   Polymer-supported organic catalysts [J].
Benaglia, M ;
Puglisi, A ;
Cozzi, F .
CHEMICAL REVIEWS, 2003, 103 (09) :3401-3429
[8]   THE CHEMISTRY AND SOLID-STATE PROPERTIES OF NICKEL, PALLADIUM AND PLATINUM BIS(MALEONITRILEDITHIOLATE) COMPOUNDS [J].
CLEMENSON, PI .
COORDINATION CHEMISTRY REVIEWS, 1990, 106 :171-203
[9]  
Dubinina N. S., 2003, RUSS CHEM REV, V72, P769
[10]   A study of catalyst selectivity with polymer bound palladium phosphine complexes on various solid phase synthesis supports [J].
Gilbertson, SR ;
Yamada, S .
TETRAHEDRON LETTERS, 2004, 45 (20) :3917-3920