In situ Raman study to monitor bioactive glasses reactivity

被引:30
作者
Bonino, Francesca [1 ]
Damin, Alessandro [1 ]
Aina, Valentina [1 ]
Miola, Marta [2 ]
Verne, Enrica [2 ]
Bretcanu, Oana [2 ]
Bordiga, Silvia [1 ]
Zecchina, Adriano [1 ]
Morterra, Claudio [1 ]
机构
[1] Univ Turin, Dept Inorgan Phys & Mat Chem, NIS Ctr Excellence, I-10125 Turin, Italy
[2] Politecn Torino, Dept Mat Sci & Chem Engn, I-10129 Turin, Italy
关键词
in situ Raman spectroscopy; bioactive glasses; hydroxy-carbonate apatite (HCA); TRIS solution; VIBRATIONAL-MODES; BIOGLASS((R)); CAO-P2O5-SIO2; BIOCOMPOSITE; SPECTROSCOPY; TEMPERATURE; ZIRCONIA; POWDERS; LAYERS; FTIR;
D O I
10.1002/jrs.1860
中图分类号
O433 [光谱学];
学科分类号
070207 [光学];
摘要
This work, by means of Raman spectroscopy, studies the vibrational modifications of a silica-based sol-gel bioactive glass (77S) in direct contact with a simple TRIS-buffered solution. The novelty of this contribution with respect to similar previous works consists in the adoption of an in situ setup, designed to avoid all kinds of external contamination. The time-dependent formation of the characteristic vibrational features of surface hydroxy-carbonate apatite (HCA) is evidenced, and followed as a function of contact time. Copyright (C) 2007 John Wiley & Sons, Ltd.
引用
收藏
页码:260 / 264
页数:5
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