Linear terpyridine-ruthenium(II) poly(ethylene glycol) coordination polymers

被引：86

作者：

Hofmeier, H

Schmatloch, S

Wouters, D

Schubert, US

机构：

[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands

[2] Dutch Polymer Inst, NL-5600 MB Eindhoven, Netherlands

[3] Univ Munich, Ctr Nanosci, D-80333 Munich, Germany

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2003年 / 204卷 / 18期

关键词：

AFM; coordination polymer; metal-polymer complexes; polyelectrolytes; poly(ethylene glycol);

D O I：

10.1002/macp.200300011

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In the present contribution, we synthesized linear coordination polymers based on oligo(ethylene glycol)s as well as poly (ethylene glycol)s and terpyridine ruthenium (II) complexes. The reaction conditions, e.g., solvent, concentration, were varied to obtain well-soluble, high molecular weight polymers. The resulting compounds were characterized by UV-vis and NMR spectroscopy. The viscosity of the materials was also investigated with and without salt addition. Finally, the polymers were characterized with DSC and AFM. AFM revealed a lamellar morphology.

引用

页码：2197 / 2203

页数：7

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