Development of a new benzo(1,2-b:4,5-b′)dithiophene-based copolymer with conjugated dithienylbenzothiadiazole-vinylene side chains for efficient solar cells

被引:64
作者
Gu, Zhaojie [1 ,2 ]
Shen, Ping [1 ,2 ]
Tsang, Sai-Wing [3 ]
Tao, Ye [3 ]
Zhao, Bin [1 ,2 ]
Tang, Peng [1 ,2 ]
Nie, Yujuan [1 ,2 ]
Fang, Yan [1 ,2 ]
Tan, Songting [1 ,2 ]
机构
[1] Xiangtan Univ, Coll Chem, Xiangtan 411105, Peoples R China
[2] Xiangtan Univ, Key Lab Adv Funct Polymer Mat, Key Lab Environm Friendly Chem & Applicat, Coll Hunan Prov,Minist Educ, Xiangtan 411105, Peoples R China
[3] Natl Res Council Canada, Inst Microstruct Sci, Ottawa, ON K1A 0R6, Canada
基金
高等学校博士学科点专项科研基金;
关键词
POLYMER PHOTOVOLTAIC MATERIALS; POLY(P-PHENYLENEVINYLENE) DERIVATIVES; PERFORMANCE; BANDGAP; HETEROJUNCTIONS; TRIPHENYLAMINE; LEVEL;
D O I
10.1039/c1cc12851e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new benzodithiophene-based copolymer PTG1 with dithienylbenzothiadiazole-vinylene side chains exhibits excellent film-forming ability, a deep HOMO energy level, and a good miscibility with PC(71)BM. Bulk heterojunction polymer solar cells fabricated from PTG1 and PC(71)BM showed a promising power conversion efficiency over 4.0%.
引用
收藏
页码:9381 / 9383
页数:3
相关论文
共 33 条
[1]   Electrochemical properties and electronic structures of conjugated polyquinolines and polyanthrazolines [J].
Agrawal, AK ;
Jenekhe, SA .
CHEMISTRY OF MATERIALS, 1996, 8 (02) :579-589
[2]   Efficient Solar Cells Based on an Easily Accessible Diketopyrrolopyrrole Polymer [J].
Bijleveld, Johan C. ;
Gevaerts, Veronique S. ;
Di Nuzzo, Daniele ;
Turbiez, Mathieu ;
Mathijssen, Simon G. J. ;
de Leeuw, Dago M. ;
Wienk, Martijn M. ;
Janssen, Rene A. J. .
ADVANCED MATERIALS, 2010, 22 (35) :E242-+
[3]   Toward a rational design of poly(2,7-carbazole) derivatives for solar cells [J].
Blouin, Nicolas ;
Michaud, Alexandre ;
Gendron, David ;
Wakim, Salem ;
Blair, Emily ;
Neagu-Plesu, Rodica ;
Belletete, Michel ;
Durocher, Gilles ;
Tao, Ye ;
Leclerc, Mario .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (02) :732-742
[4]   Processable Low-Bandgap Polymers for Photovoltaic Applications [J].
Boudreault, Pierre-Luc T. ;
Najari, Ahmed ;
Leclerc, Mario .
CHEMISTRY OF MATERIALS, 2011, 23 (03) :456-469
[5]   Polymer solar cells with enhanced open-circuit voltage and efficiency [J].
Chen, Hsiang-Yu ;
Hou, Jianhui ;
Zhang, Shaoqing ;
Liang, Yongye ;
Yang, Guanwen ;
Yang, Yang ;
Yu, Luping ;
Wu, Yue ;
Li, Gang .
NATURE PHOTONICS, 2009, 3 (11) :649-653
[6]   Development of Novel Conjugated Donor Polymers for High-Efficiency Bulk-Heterojunction Photovoltaic Devices [J].
Chen, Junwu ;
Cao, Yong .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1709-1718
[7]   Synthesis of Conjugated Polymers for Organic Solar Cell Applications [J].
Cheng, Yen-Ju ;
Yang, Sheng-Hsiung ;
Hsu, Chain-Shu .
CHEMICAL REVIEWS, 2009, 109 (11) :5868-5923
[8]   Effect of Alkyl Side-Chain Length on Photovoltaic Properties of Poly(3-alkylthiophene)/PCBM Bulk Heterojunctions [J].
Gadisa, Abay ;
Oosterbaan, Wibren D. ;
Vandewal, Koen ;
Bolsee, Jean-Christophe ;
Bertho, Sabine ;
D'Haen, Jan ;
Lutsen, Laurence ;
Vanderzande, Dirk ;
Manca, Jean V. .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (20) :3300-3306
[9]   Tetrathienoanthracene-Based Copolymers for Efficient Solar Cells [J].
He, Feng ;
Wang, Wei ;
Chen, Wei ;
Xu, Tao ;
Darling, Seth B. ;
Strzalka, Joseph ;
Liu, Yun ;
Yu, Luping .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (10) :3284-3287
[10]   Synthesis and photovoltaic properties of two-dimensional conjugated polythiophenes with bi(thienylenevinylene) side chains [J].
Hou, JH ;
Tan, ZA ;
Yan, Y ;
He, YJ ;
Yang, CH ;
Li, YF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (14) :4911-4916