Tetrathienoanthracene-Based Copolymers for Efficient Solar Cells

被引：138

作者：

He, Feng ^{[1
,2
]}

Wang, Wei ^{[1
,2
]}

Chen, Wei ^{[3
]}

Xu, Tao ^{[1
,2
]}

Darling, Seth B. ^{[3
]}

Strzalka, Joseph ^{[4
]}

Liu, Yun ^{[5
,6
]}

Yu, Luping ^{[1
,2
]}

机构：

[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA

[2] Univ Chicago, James Franck Inst, Chicago, IL 60637 USA

[3] Argonne Natl Lab, Ctr Nanoscale Mat, Argonne, IL 60439 USA

[4] Argonne Natl Lab, Adv Photon Source, Xray Sci Div, Argonne, IL 60439 USA

[5] Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA

[6] Univ Delaware, Dept Chem Engn, Newark, DE 19716 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 10期

基金：

美国国家科学基金会;

关键词：

POWER CONVERSION EFFICIENCY; POLYMER PHOTOVOLTAIC CELLS; SEMICONDUCTING POLYMERS; PERFORMANCE;

D O I：

10.1021/ja1110915

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of semiconducting copolymers (PTAT-x) containing extended pi-conjugated tetrathienoanthracene units have been synthesized. It was shown that the extended conjugation system enhanced the pi-pi stacking in the polymer/PC61 BM blend films and facilitated the charge transport in heterojunction solar cell devices. After structural fine-tuning, the polymer with bulky 2-butyloctyl side chains (PTAT-3) exhibited a PCE of 5.6% when it was blended with PC61BM.

引用

页码：3284 / 3287

页数：4

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