共 23 条
Tetrathienoanthracene-Based Copolymers for Efficient Solar Cells
被引:138
作者:
He, Feng
[1
,2
]
Wang, Wei
[1
,2
]
Chen, Wei
[3
]
Xu, Tao
[1
,2
]
Darling, Seth B.
[3
]
Strzalka, Joseph
[4
]
Liu, Yun
[5
,6
]
Yu, Luping
[1
,2
]
机构:
[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA
[2] Univ Chicago, James Franck Inst, Chicago, IL 60637 USA
[3] Argonne Natl Lab, Ctr Nanoscale Mat, Argonne, IL 60439 USA
[4] Argonne Natl Lab, Adv Photon Source, Xray Sci Div, Argonne, IL 60439 USA
[5] Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA
[6] Univ Delaware, Dept Chem Engn, Newark, DE 19716 USA
基金:
美国国家科学基金会;
关键词:
POWER CONVERSION EFFICIENCY;
POLYMER PHOTOVOLTAIC CELLS;
SEMICONDUCTING POLYMERS;
PERFORMANCE;
D O I:
10.1021/ja1110915
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
A series of semiconducting copolymers (PTAT-x) containing extended pi-conjugated tetrathienoanthracene units have been synthesized. It was shown that the extended conjugation system enhanced the pi-pi stacking in the polymer/PC61 BM blend films and facilitated the charge transport in heterojunction solar cell devices. After structural fine-tuning, the polymer with bulky 2-butyloctyl side chains (PTAT-3) exhibited a PCE of 5.6% when it was blended with PC61BM.
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页码:3284 / 3287
页数:4
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