A new cyclometalation motif: Synthesis, structure, and reactivity of palladacycles that contain a chiral rhenium fragment in the backbone and are catalyst precursors for Heck reactions

被引：15

作者：

Friedlein, FK ^{[1
]}

Hampel, F ^{[1
]}

Gladysz, JA ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 17期

关键词：

D O I：

10.1021/om0504708

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of (R)-[(eta(5)-C5H5)Re(NO)(PPh3)(CH2-PPh2H)]X-+(-), mild base, and Pd(OAc)(2) yield the novel Pd-3(OAc)(4)-based palladacycle (R,R)-(eta 5-C5H4)Re(NO)-(PPh3)(mu-CH2PPh2)Pd(mu-OAc)(2)Pd(mu-OAc)(2)Pd(mu-PPh2CH2)-Re(Ph3P)(ON)(eta 5-C5H4), which has been characterized crystallographically and elaborated to dimeric halide-bridged and monomeric palladacycles that are effective catalyst precursors for the Heck reaction.

引用

页码：4103 / 4105

页数：3

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