Progress in stereoselective catalysis by metal complexes with chiral ferrocenyl phosphines

被引:205
作者
Barbaro, P [1 ]
Bianchini, C [1 ]
Giambastiani, G [1 ]
Parisel, SL [1 ]
机构
[1] CNR, Ist Chim Composti OrganoMet, I-50019 Sesto Fiorentino, Firenze, Italy
关键词
C-1-symmetric diphosphines; ferrocenyl phosphines; asymmetric catalysis; catalyst immobilization;
D O I
10.1016/j.ccr.2004.03.022
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This review covers recent achievements in homogeneous and single-site heterogeneous asymmetric catalysis by metal complexes containing stereohomogeneous ferrocenyl phosphine ligands. The processes reviewed include: reductions of various prochiral substrates, allylic substitutions, hydrosilylations, hydroformylations, hydroaminations and hydroborations. Particular attention has been paid to studies aimed at designing novel ligand architectures as well as identifying active catalytic species. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:2131 / 2150
页数:20
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