Progress in stereoselective catalysis by metal complexes with chiral ferrocenyl phosphines

被引：205

作者：

Barbaro, P ^{[1
]}

Bianchini, C ^{[1
]}

Giambastiani, G ^{[1
]}

Parisel, SL ^{[1
]}

机构：

[1] CNR, Ist Chim Composti OrganoMet, I-50019 Sesto Fiorentino, Firenze, Italy

来源：

COORDINATION CHEMISTRY REVIEWS | 2004年 / 248卷 / 21-24期

关键词：

C-1-symmetric diphosphines; ferrocenyl phosphines; asymmetric catalysis; catalyst immobilization;

D O I：

10.1016/j.ccr.2004.03.022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review covers recent achievements in homogeneous and single-site heterogeneous asymmetric catalysis by metal complexes containing stereohomogeneous ferrocenyl phosphine ligands. The processes reviewed include: reductions of various prochiral substrates, allylic substitutions, hydrosilylations, hydroformylations, hydroaminations and hydroborations. Particular attention has been paid to studies aimed at designing novel ligand architectures as well as identifying active catalytic species. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：2131 / 2150

页数：20

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