Intriguing coordination behaviors of aquo and amine ligands bound to the organoruthenium(II) cation [Ru(eta(6)-C6H6)(bpop)](2+) (bpop=2,2-bis[4(R)-phenyl-1,3-oxazolon-2-yl]propane)

被引:34
作者
Asano, H [1 ]
Katayama, K [1 ]
Kurosawa, H [1 ]
机构
[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN
关键词
D O I
10.1021/ic960410h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Dissociation of the Ru-O bond of coordinated water in the aquaruthenium complex 1 (L = H2O) was slower in acetone-db than in CD2Cl2, as evidenced by variable-temperature NMR experiments. The two N-hydrogens of the coordinated RNH(2) in the amine complex 4 (L = NH(2)Bu) underwent deuterium exchange in CD3OD with greatly different rates.
引用
收藏
页码:5760 / &
页数:3
相关论文
共 14 条