RUTHENIUM-CATALYZED SYNTHESIS OF UNSATURATED ACETALS AND ALDEHYDES VIA C-C BOND COUPLING OF ALKYNES WITH ALLYL ALCOHOL

被引：37

作者：

DERIEN, S ^{[1
]}

DIXNEUF, PH ^{[1
]}

机构：

[1] UNIV RENNES 1,CHIM COORDINAT ORGAN LAB,CNRS,URA 415,F-35042 RENNES,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 22期

关键词：

D O I：

10.1039/c39940002551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Terminal alkynes and allyl alcohol are coupled, with carbon-carbon bond formation, in the presence of a Ru-IV(C(5)Me(5)) catalyst, to give gamma,delta-unsaturated acetals and with [{RuCl(CMe(5))}(4)] Or [RuCl(cod)(C(5)Me(5))] preferentially to produce the branched gamma,delta-unsaturated aldehydes.

引用

页码：2551 / 2552

页数：2

共 22 条

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