Surface modifications of polyvinylidene fluoride (PVDF) under rf Ar plasma

被引：124

作者：

Duca, MD

Plosceanu, CL

Pop, T

机构：

[1] Univ Bucharest, Fac Chem, Dept Phys, Bucharest 1, Romania

[2] Univ Politehn Bucuresti, Dept Phys, Bucharest 6, Romania

来源：

POLYMER DEGRADATION AND STABILITY | 1998年 / 61卷 / 01期

关键词：

D O I：

10.1016/S0141-3910(97)00130-4

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The surface modifications of polyvinylidene fluoride (PVDF) induced by rf Ar plasma treatment have been investigated using X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM). Water contact angle measurements on PVDF surfaces were also performed. The XPS analysis shows that the plasma treatment causes dehydrofluorination of PVDF and the incorporation of oxygen into the polymer surface, while the AFM images reveal surface roughening. Contact angle measurements and surface free energy calculations show an improvement in the PVDF surface wettability after the plasma treatment. The decrease of F(1s)/C(1s) ratio and water contact angle and the increase of surface roughness and free energy for rf Ar plasma-treated PVDF prove that both chemical and physical effects play an important role in the adhesion. (C) 1998 Elsevier Science Limited. All rights reserved.

引用

页码：65 / 72

页数：8

共 23 条

[21] CHEMICAL AND PHYSICAL MODIFICATION OF FLUOROPOLYMER SURFACES FOR ADHESION ENHANCEMENT - A REVIEW [J].