Synthesis of constrained-geometry chiral Di-N-heterocyclic carbene ligands and their silver(I) and palladium(II) complexes

被引：121

作者：

Bonnet, LG ^{[1
]}

Douthwaite, RE ^{[1
]}

Hodgson, R ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 22期

关键词：

D O I：

10.1021/om030527v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silver(I) and palladium(II) complexes of constrained-geometry chiral di-N-heterocyclic carbenes have been prepared from trans-1,2-diaminocyclohexane via the base-induced 1,3-cycloaddition of tosylmethyl isocyanide to diimines.

引用

页码：4384 / 4386

页数：3

共 40 条

[1] THE DEVELOPMENT OF VERSION-3 AND VERSION-4 OF THE CAMBRIDGE STRUCTURAL DATABASE SYSTEM
ALLEN, FH
DAVIES, JE
GALLOY, JJ
JOHNSON, O
KENNARD, O
MACRAE, CF
MITCHELL, EM
MITCHELL, GF
SMITH, JM
WATSON, DG
[J]. JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES, 1991, 31 (02): : 187 - 204
[2] Broggini D, 2002, HELV CHIM ACTA, V85, P2518, DOI 10.1002/1522-2675(200208)85:8<2518::AID-HLCA2518>3.0.CO
[3] 2-N
[4] First chelated chiral N-Heterocyclic bis-carbene complexes
Clyne, DS
Jin, J
Genest, E
Gallucci, JC
RajanBabu, TV
[J]. ORGANIC LETTERS, 2000, 2 (08) : 1125 - 1128
[5] ROUTES TO OPTICALLY-ACTIVE ELECTRON-RICH OLEFINS (L-STAR-2) AND SOME DERIVED CARBENEMETAL COMPLEXES - X-RAY STRUCTURES OF [CO(CO)(L-STAR)(NO)(PPH3)] AND CIS-[RH(CL)(COD)(L'STAR)] [L-STAR= (S)-CN(ME)CH(ME)H2NME, L'STAR=(S)-CN(CH2CH2CH2)CHCH2NME, COD=1,5-C8H12]
COLEMAN, AW
HITCHCOCK, PB
LAPPERT, MF
MASKELL, RK
MULLER, JH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 250 (01) : C9 - C14
[6] Synthesis of chiral triazolinylidene and imidazolinylidene transition metal complexes and first application in asymmetric catalysis
Enders, D
Gielen, H
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 617 (01) : 70 - 80
[7] Synthesis and stereochemistry of the first chiral (imidazolinylidene)- and (triazolinylidene)palladium(II) complexes
Enders, D
Gielen, H
Raabe, G
Runsink, J
Teles, JH
[J]. CHEMISCHE BERICHTE-RECUEIL, 1996, 129 (12): : 1483 - 1488
[8] Gilchrist T.L., 1992, HETEROCYCLIC CHEM, V2nd
[9] Oxazolines as chiral building blocks for imidazolium salts and N-heterocyclic carbene ligands
Glorius, F
Altenhoff, G
Goddard, R
Lehmann, C
[J]. CHEMICAL COMMUNICATIONS, 2002, (22) : 2704 - +
[10] Enantioselective copper-catalyzed conjugate addition using chiral diaminocarbene ligands
Guillen, F
Winn, CL
Alexakis, A
[J]. TETRAHEDRON-ASYMMETRY, 2001, 12 (15) : 2083 - 2086

← 1 2 3 4 →