Synthesis of constrained-geometry chiral Di-N-heterocyclic carbene ligands and their silver(I) and palladium(II) complexes

被引:121
作者
Bonnet, LG [1 ]
Douthwaite, RE [1 ]
Hodgson, R [1 ]
机构
[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
关键词
D O I
10.1021/om030527v
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Silver(I) and palladium(II) complexes of constrained-geometry chiral di-N-heterocyclic carbenes have been prepared from trans-1,2-diaminocyclohexane via the base-induced 1,3-cycloaddition of tosylmethyl isocyanide to diimines.
引用
收藏
页码:4384 / 4386
页数:3
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