Detection of CuII by a chemodosimeter-functionalized monolayer on mesoporous silica

被引:104
作者
Kim, Hyun Jung [3 ]
Lee, Soo Jin [1 ,2 ]
Park, Sun Young [3 ]
Jung, Jong Hwa [1 ,2 ]
Kim, Jong Seung [3 ]
机构
[1] Gyeongsang Natl Univ, Dept Chem, Jinju 660701, South Korea
[2] Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 660701, South Korea
[3] Korea Univ, Dept Chem, Seoul 136701, South Korea
关键词
D O I
10.1002/adma.200800246
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first Cu-II-induced cyclic guanylation of thiourea anthraquinone (1), exhibiting high selectivity towards Cu-II over other competitive cations in aspects of fluorometric and colorimetric chemodosimetry, is reported. Moreover, mesoporous silica-immobilized anthraquinone (MSIA) is also fabricated and shows Cu2+ ion selectivity with respect to a color change from red to yellow.
引用
收藏
页码:3229 / +
页数:7
相关论文
共 42 条
[1]   Optical sensors based on nanostructured cage materials for the detection of toxic metal ions [J].
Balaji, Tatineni ;
El-Safty, Sherif A. ;
Matsunaga, Hideyuki ;
Hanaoka, Takaaki ;
Mizukami, Fujio .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (43) :7202-7208
[2]   Excited state intramolecular proton transfer in 2-(2'-hydroxyphenyl)-1H-imidazo[4,5-c]pyridine: effects of solvents [J].
Balamurali, MM ;
Dogra, SK .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 154 (01) :81-92
[3]   A colorimetric ligand for mercuric ion [J].
Brummer, O ;
La Clair, JJ ;
Janda, KD .
ORGANIC LETTERS, 1999, 1 (03) :415-418
[4]  
BRZOZKA Z, 1996, COMPREHENSIVE SUPRAM, V10, P187
[5]   FLUOROMETRIC CHEMODOSIMETRY - MERCURY(II) AND SILVER(I) INDICATION IN WATER VIA ENHANCED FLUORESCENCE SIGNALING [J].
CHAE, MY ;
CZARNIK, AW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (24) :9704-9705
[6]   Reversible colorimetric probes for mercury sensing [J].
Coronado, E ;
Galán-Mascaros, JR ;
Martí-Gastaldo, C ;
Palomares, E ;
Durrant, JR ;
Vilar, R ;
Gratzel, M ;
Nazeeruddin, MK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (35) :12351-12356
[7]  
Czarnik A.W., 1993, ACS S SERIES
[8]   Photophysical properties of 1-N-methylamino- and 1-N,N-dimethylamino-9,10-anthraquinone dyes:: A comparison with 1-amino-9,10-anthraquinone dye [J].
Dahiya, P. ;
Maity, D. K. ;
Nayak, S. K. ;
Mukherjee, T. ;
Pal, H. .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2007, 186 (2-3) :218-228
[9]   Solvent polarity and intramolecular hydrogen bonding effects on the photophysical properties of 1-amino-9,10-anthraquinone dye [J].
Dahiya, P. ;
Kumbhakar, M. ;
Maity, D. K. ;
Mukherjee, T. ;
Tripathi, A. B. R. ;
Chattopadhyay, N. ;
Pal, H. .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2006, 181 (2-3) :338-347
[10]   Signaling recognition events with fluorescent sensors and switches [J].
de Silva, AP ;
Gunaratne, HQN ;
Gunnlaugsson, T ;
Huxley, AJM ;
McCoy, CP ;
Rademacher, JT ;
Rice, TE .
CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566