Anion complexation of vinylimidazolium salts and its influence on polymerization

被引：65

作者：

Amajjahe, Sadik ^{[1
]}

Ritter, Helmut ^{[1
]}

机构：

[1] Univ Dusseldorf, Dept Preparat Polymer Chem, Inst Organ Chem & Macromol Chem 2, D-40225 Dusseldorf, Germany

来源：

MACROMOLECULES | 2008年 / 41卷 / 03期

关键词：

D O I：

10.1021/ma702271p

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

To improve water solubility of 1-butyl-3-vinylimidazolium bis(trifluoromethylsulfonyl)imide ([bvim]-[Tf2N]) the complexation with beta-Cyclodextrin (beta-CD) was carried out. Investigations of conductivity measurements, NMR and microcalorimetry show that beta-CD forms exclusively host-guest complexes with the anion bis(trifluoromethylsulfonyl)imide (Tf2N-). The received spatially separated ion pairs create quasi "naked" vinylimidazolium cations which do not polymerize in water by radical mechanism. Only in the presence of foreign salt is the cation-cation repulsion compensated and polymerization occurs.

引用

页码：716 / 718

页数：3

共 25 条

[21] ENTHALPY AND ENTROPY CHANGES ON MOLECULAR INCLUSION OF 1,3-BUTANEDIOL INTO ALPHA-CYCLODEXTRIN AND BETA-CYCLODEXTRIN CAVITIES IN AQUEOUS-SOLUTIONS [J].