A facile and patternable method for the surface modification of carbon nanotube forests using perfluoroarylazides

被引：147

作者：

Pastine, Stefan J. ^{[1
]}

Okawa, David ^{[1
,2
]}

Kessler, Brian ^{[2
]}

Rolandi, Marco ^{[1
,3
]}

Llorente, Mark ^{[2
]}

Zettl, Alex ^{[2
,3
]}

Frechet, Jean M. J. ^{[1
,3
]}

机构：

[1] Univ Calif Berkeley, Coll Chem, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA

[3] Univ Calif Berkeley, Div Mat Sci, Berkeley, CA 94720 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 13期

关键词：

D O I：

10.1021/ja8003446

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile patterning method for the functionalization of vertically aligned carbon nanotubes; is described. Modification of the surface of nanotube forests with hydrophilic, hydrophobic, or polymerizable small molecules was achieved via UV-triggered attachment of perfluoroarylazides. Multiple functionalizations; of the tube surface can be achieved. Macro- and micropatterning of forest substrates were demonstrated. Superhydrophobic surfaces containing superhydrophilic regions were prepared.

引用

页码：4238 / +

页数：3

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