Liquid-liquid equilibria for systems composed by 1-methyl-3-octylimidazolium tetrafluoroborate ionic liquid, thiophene, and n-hexane or cyclohexane

被引：54

作者：

Alonso, Luisa ^{[1
]}

Arce, Alberto ^{[1
]}

Francisco, Maria ^{[1
]}

Rodriguez, Oscar ^{[1
]}

Soto, Ana ^{[1
]}

机构：

[1] Univ Santiago de Compostela, Dept Chem Engn, E-15782 Santiago De Compostela, Spain

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2007年 / 52卷 / 05期

关键词：

D O I：

10.1021/je700126z

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Liquid-liquid equilibrium data have been determined experimentally for {1-methyl-3-octylimidazolium tetrafluoroborate + thiophene + hexane} and {1-methyl-3-octylimidazolium tetrafluoroborate + thiophene + cyclohexane} ternary systems at 298.15 K. The compositions of the ends of the tie-lines were obtained by gas chromatographic analysis of phases at equilibrium. Data have been adequately correlated using the nonrandom two-liquid (NRTL) activity coefficient model despite this being an equation intended for nonelectrolyte solutions.

引用

页码：1729 / 1732

页数：4

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